DIY History | Transcribe | Scholarship at Iowa | Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892 | Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892, Page 38

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Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892

Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892, Page 38

[page]37[/page]

HNO[subscript]3[/subscript] + H[subscript]2[/subscript] = HNO[subscript]2[/subscript] + H[subscript]2[/subscript]O.

HNO[subscript]2[/subscript] + H[subscript]2[/subscript] = HNO + H[subscript]2[/subscript]O.

HNO + H[subscript]2[/subscript] = NH[subscript]2[/subscript](OH).

HN[subscript]2[/subscript](OH) + H[subscript]2[/subscript] = NH[subscript]3[/subscript] + H[subscript]2[/subscript]O.

Hydroxylamine behaves very differently from ammonia towards the halogens. Hydroxylamine, when in the liquid state, dissolves salts and on evaporation the salt is thrown down. For example, L. Crismer found that, on heating zinc chloride and hydroxylamine, ZnCl[subscript]2[/subscript](NH[subscript]3[/subscript]OH)[subscript]2[/subscript] , the [?illegible?] distilled off could be condensed in a receiver.

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[page]37[/page] HNO[subscript]3[/subscript] + H[subscript]2[/subscript] = HNO[subscript]2[/subscript] + H[subscript]2[/subscript]O. HNO[subscript]2[/subscript] + H[subscript]2[/subscript] = HNO + H[subscript]2[/subscript]O. HNO + H[subscript]2[/subscript] = NH[subscript]2[/subscript](OH). HN[subscript]2[/subscript](OH) + H[subscript]2[/subscript] = NH[subscript]3[/subscript] + H[subscript]2[/subscript]O. Hydroxylamine behaves very differently from ammonia towards the halogens. Hydroxylamine, when in the liquid state, dissolves salts and on evaporation the salt is thrown down. For example, L. Crismer found that, on heating zinc chloride and hydroxylamine, ZnCl[subscript]2[/subscript](NH[subscript]3[/subscript]OH)[subscript]2[/subscript] , the [?illegible?] distilled off could be condensed in a receiver.