DIY History | Transcribe | Scholarship at Iowa | Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892 | Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892, Page 45

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Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892

Derivatives of Hydroxylamine by Agnes Elizabeth Otto, 1892, Page 45

[page]44[/page]

potassium salts are used. If performed very quickly, the sulphites can easily be separated from the nitrites by precipitation as barium salt. The metasulphite and nitrite are neutral when separate, but together give an alkaline reaction and absorb carbonic anhydride. --
NaNO[subscript]2[/subscript] + 2SO[subscript]3[/subscript][?Ba?][subscript]2[/subscript] + 3C[?O?][subscript]2[/subscript] + 2H[subscript]2[/subscript]O = HON(SO[subscript]3[/subscript]Na)[subscript]2[/subscript] + 3C[?O?][subscript]3[/subscript]NaH.
HON(SO[subscript]3[/subscript]Na)[subscript]2[/subscript] + SO[subscript]3[/subscript]Na[subscript]2[/subscript] + CO[subscript]2[/subscript] = N(SO[subscript]3[/subscript]Na)[subscript]3[/subscript] + CO[subscript]3[/subscript]NaH.
     [underlined]The Constitution of Hyponitrites is explained by the Decomposition of Hydroxylamine-monosulphonate:--[/underlined]

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[page]44[/page] potassium salts are used. If performed very quickly, the sulphites can easily be separated from the nitrites by precipitation as barium salt. The metasulphite and nitrite are neutral when separate, but together give an alkaline reaction and absorb carbonic anhydride. -- NaNO[subscript]2[/subscript] + 2SO[subscript]3[/subscript][?Ba?][subscript]2[/subscript] + 3C[?O?][subscript]2[/subscript] + 2H[subscript]2[/subscript]O = HON(SO[subscript]3[/subscript]Na)[subscript]2[/subscript] + 3C[?O?][subscript]3[/subscript]NaH. HON(SO[subscript]3[/subscript]Na)[subscript]2[/subscript] + SO[subscript]3[/subscript]Na[subscript]2[/subscript] + CO[subscript]2[/subscript] = N(SO[subscript]3[/subscript]Na)[subscript]3[/subscript] + CO[subscript]3[/subscript]NaH. [underlined]The Constitution of Hyponitrites is explained by the Decomposition of Hydroxylamine-monosulphonate:--[/underlined]