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Phenylbromethylbenzenesulfonamid and phenylbromethylamin by Carl Leopold von Ende, 1893

Phenylbromethylbenzenesulfonamide and Phenylbromethylamin by Carl Leopold von Ende, 1893, Page 2

[pencil label]Archives
T.1893
E563[/pencil label]

[page]1.[/page]

[underline]The Amino[/underline][superscript]#[/superscript]
The carbon derivatives include a class of very basic compounds, called organic bases or alkaloids. They all contain nitrogen and are looked upon as derivatives of ammonia, which accounts for their basic properties. One, Two or three of the hydrogen atoms being replacable by alkyls, gives rise respectively to primary, secondary and tertiary amins.

NH[subscript]2[/subscript] * CH[subscript]3[/subscript] Primary methylamin
 
NH  * (CH[subscript]3[/subscript])[subscript]2[/subscript] Secondary " [ditto for methylamin]

N (CH)[subscript]3[/subscript] Tertiary " [ditto for methylamin]

There are likewise derivatives corresponding to NH[subscript]4[/subscript] * Cl and hypothetical NH[subscript]4[/subscript] * OH

N(CH[subscript]3[/subscript])[subscript]4[/subscript]Cl 

Tetramethylammoniumchlorid.

N(CH[subscript]3[/subscript])[subscript]4[/subscript]OH 

Tetramethylammoniumhydrate. 

# Roscoe & [?Schorlem?lan? Richter?]

[marked]48577[/marked]

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[pencil label]Archives T.1893 E563[/pencil label] [page]1.[/page] [underline]The Amino[/underline][superscript]#[/superscript] The carbon derivatives include a class of very basic compounds, called organic bases or alkaloids. They all contain nitrogen and are looked upon as derivatives of ammonia, which accounts for their basic properties. One, Two or three of the hydrogen atoms being replacable by alkyls, gives rise respectively to primary, secondary and tertiary amins. NH[subscript]2[/subscript] * CH[subscript]3[/subscript] Primary methylamin NH * (CH[subscript]3[/subscript])[subscript]2[/subscript] Secondary " [ditto for methylamin] N (CH)[subscript]3[/subscript] Tertiary " [ditto for methylamin] There are likewise derivatives corresponding to NH[subscript]4[/subscript] * Cl and hypothetical NH[subscript]4[/subscript] * OH N(CH[subscript]3[/subscript])[subscript]4[/subscript]Cl Tetramethylammoniumchlorid. N(CH[subscript]3[/subscript])[subscript]4[/subscript]OH Tetramethylammoniumhydrate. # Roscoe & [?Schorlem?lan? Richter?] [marked]48577[/marked]