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Phenylbromethylbenzenesulfonamid and phenylbromethylamin by Carl Leopold von Ende, 1893

Phenylbromethylbenzenesulfonamide and Phenylbromethylamin by Carl Leopold von Ende, 1893, Page 5

[page]4[/page]

They separate, like NH[subscript]4[/subscript]Cl, into their constituents upon heating, but recombine again upon cooling. Moist silver oxid converts them into hydrates, which are strong alkalies like NaOH or KOH[subscript]1[/subscript] readily soluble in water, form crystalline salts, throw down many metals from solutions as hydrates, destroy animal matter, such as skin, and saponify fats.
     The possible isomers of the [?aurnis?] are very numerous; they are determined not only by the isomers of the alkyls, but also by the number of replacing groups, as the following examples will show.

NH[subscript]2[/subscript] * C[subscript]3[/subscript]H[subscript]7[/subscript]

Propyl and Isopropylamin.

NH * [branch1]C[subscript]2[/subscript]H[subscript]5[/subscript][/branch1][branch2]CH[subscript]3[/subscript][/branch2]

Methylethylamin

N(CH[subscript]3[/subscript])[subscript]3[/subscript]

Trimethylamin

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[page]4[/page] They separate, like NH[subscript]4[/subscript]Cl, into their constituents upon heating, but recombine again upon cooling. Moist silver oxid converts them into hydrates, which are strong alkalies like NaOH or KOH[subscript]1[/subscript] readily soluble in water, form crystalline salts, throw down many metals from solutions as hydrates, destroy animal matter, such as skin, and saponify fats. The possible isomers of the [?aurnis?] are very numerous; they are determined not only by the isomers of the alkyls, but also by the number of replacing groups, as the following examples will show. NH[subscript]2[/subscript] * C[subscript]3[/subscript]H[subscript]7[/subscript] Propyl and Isopropylamin. NH * [branch1]C[subscript]2[/subscript]H[subscript]5[/subscript][/branch1][branch2]CH[subscript]3[/subscript][/branch2] Methylethylamin N(CH[subscript]3[/subscript])[subscript]3[/subscript] Trimethylamin