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Phenylbromethylbenzenesulfonamid and phenylbromethylamin by Carl Leopold von Ende, 1893

Phenylbromethylbenzenesulfonamide and Phenylbromethylamin by Carl Leopold von Ende, 1893, Page 12

[page]11.[/page]

amins; hence the former are easily decomposed, by heating with water or still more easily by boiling with alkalies or acids.

CH[subscript]3[/subscript] * CO * NH[subscript]2[/subscript] + H[subscript]2[/subscript]O = CH[subscript]3[/subscript] * COH + NH[subscript]3[/subscript]

[underlined]Formamid[/underlined] CHO * NH[subscript]2[/subscript]

     It is the amid of formic acid and is obtained by heating ammonium formate to 230 degrees or ethyl-formic ester with alcoholic NH[subscript]3[/subscript] to 100 degrees or by boiling formic acid with ammonium sulfocyamid. It is a liquid readily soluble in water and alcohol and boils at 192 degrees -- 195 degrees with partial decomposition. Rapid heating breaks it up into CO and NH[subscript]3[/subscript] and with P[subscript]2[/subscript]O[subscript]5[/subscript] gives HCN.

[underlined]Acetamid[/underlined] C[subscript]2[/subscript]H[subscript]3[/subscript]O * NH[subscript]2[/subscript]

     It is the amid of acetic acid and is formed by heating a mixture of dry sodium acetate and NH[subscript]4[/subscript]Cl or by digesting acetic ester with alcoholic NH[subscript]3[/subscript]

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[page]11.[/page] amins; hence the former are easily decomposed, by heating with water or still more easily by boiling with alkalies or acids. CH[subscript]3[/subscript] * CO * NH[subscript]2[/subscript] + H[subscript]2[/subscript]O = CH[subscript]3[/subscript] * COH + NH[subscript]3[/subscript] [underlined]Formamid[/underlined] CHO * NH[subscript]2[/subscript] It is the amid of formic acid and is obtained by heating ammonium formate to 230 degrees or ethyl-formic ester with alcoholic NH[subscript]3[/subscript] to 100 degrees or by boiling formic acid with ammonium sulfocyamid. It is a liquid readily soluble in water and alcohol and boils at 192 degrees -- 195 degrees with partial decomposition. Rapid heating breaks it up into CO and NH[subscript]3[/subscript] and with P[subscript]2[/subscript]O[subscript]5[/subscript] gives HCN. [underlined]Acetamid[/underlined] C[subscript]2[/subscript]H[subscript]3[/subscript]O * NH[subscript]2[/subscript] It is the amid of acetic acid and is formed by heating a mixture of dry sodium acetate and NH[subscript]4[/subscript]Cl or by digesting acetic ester with alcoholic NH[subscript]3[/subscript]