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Phenylbromethylbenzenesulfonamid and phenylbromethylamin by Carl Leopold von Ende, 1893

Phenylbromethylbenzenesulfonamide and Phenylbromethylamin by Carl Leopold von Ende, 1893, Page 13

[page]12.[/page]

It crystallizes in long needles, melts at 82 degrees -- 83 degrees and boils with decomposition at 222 degrees. It readily dissolves in water and alcohol and when boiled with alkalies or acids decomposes into acetic acid and NH[subscript]3[/subscript].

   [underlined]The Sulfonamids.[/underlined]

     According to Hinsberg (see Liebig's [?Armalen?] Vol. 265, Pg 178 and Vol. 272, Pg 229) the amids of benzenesulfonic acid, especially benzenesulfonamid and the benzenesulfonamids of the primary bases are distinguished form almost all other acid amids, by the fact that they are strong acids and give with the alkalies easily soluble salts, whose stability is so great, in the presence of an excess of alkali, that they may be boiled for hours with concentrated NaOH or KOH without being effected.

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[page]12.[/page] It crystallizes in long needles, melts at 82 degrees -- 83 degrees and boils with decomposition at 222 degrees. It readily dissolves in water and alcohol and when boiled with alkalies or acids decomposes into acetic acid and NH[subscript]3[/subscript]. [underlined]The Sulfonamids.[/underlined] According to Hinsberg (see Liebig's [?Armalen?] Vol. 265, Pg 178 and Vol. 272, Pg 229) the amids of benzenesulfonic acid, especially benzenesulfonamid and the benzenesulfonamids of the primary bases are distinguished form almost all other acid amids, by the fact that they are strong acids and give with the alkalies easily soluble salts, whose stability is so great, in the presence of an excess of alkali, that they may be boiled for hours with concentrated NaOH or KOH without being effected.